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Syntheses and Crystal Structures of Two One-Dimensional Chain Copper Benzoylacetone Complexes Bridged Through Azobispyridine Ligands.

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    • Abstract:
      Two copper complexes [Cu(bzac) 2 (4,4′-azpy)] · H 2 O ( 1 ) and [Cu(bzac) 2 (3,3′-azpy)] ( 2 ) (bzac = benzoylacetone, 4,4′-azpy = 4,4′-azobispyridine, 3,3′-azpy = 3,3′-azobispyridine) have been synthesized and characterized. The crystal structures were determined by X-ray diffraction analysis. In crystals of Complexes 1 and 2 , the copper atoms have distorted octahedral symmetry. The two compounds possess very similar one-dimensional linear chains linked through the rod-like 4,4′-azpy or 3,3′-azpy ligands. [ABSTRACT FROM AUTHOR]
    • Abstract:
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